An escape artist called David Merlini broke the world record for the longest time underwater without air in 2007. His time was 10 minutes and 17 seconds without a breath while chained and handcuffed under water.
If you’re allowed to include people aided by technology then there are submarines that remain submerged for months at a time, with the crew underwater for the entirety of it.
If not theres a free diver who held his head underwater for 22 minutes, trashing David Merlini’s record… although everything was set up to his liking and he inhaled (almost) pure oxygen prior to going under. Also there were no chains.
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